250 research outputs found
Formation of molecular oxygen in ultracold O + OH reaction
We discuss the formation of molecular oxygen in ultracold collisions between
hydroxyl radicals and atomic oxygen. A time-independent quantum formalism based
on hyperspherical coordinates is employed for the calculations. Elastic,
inelastic and reactive cross sections as well as the vibrational and rotational
populations of the product O2 molecules are reported. A J-shifting
approximation is used to compute the rate coefficients. At temperatures T = 10
- 100 mK for which the OH molecules have been cooled and trapped
experimentally, the elastic and reactive rate coefficients are of comparable
magnitude, while at colder temperatures, T < 1 mK, the formation of molecular
oxygen becomes the dominant pathway. The validity of a classical capture model
to describe cold collisions of OH and O is also discussed. While very good
agreement is found between classical and quantum results at T=0.3 K, at higher
temperatures, the quantum calculations predict a larger rate coefficient than
the classical model, in agreement with experimental data for the O + OH
reaction. The zero-temperature limiting value of the rate coefficient is
predicted to be about 6.10^{-12} cm^3 molecule^{-1} s^{-1}, a value comparable
to that of barrierless alkali-metal atom - dimer systems and about a factor of
five larger than that of the tunneling dominated F + H2 reaction.Comment: 9 pages, 8 figure
Controlling the quantum stereodynamics of ultracold bimolecular reactions
Chemical reaction rates often depend strongly on stereodynamics, namely the
orientation and movement of molecules in three-dimensional space. An ultracold
molecular gas, with a temperature below 1 uK, provides a highly unusual regime
for chemistry, where polar molecules can easily be oriented using an external
electric field and where, moreover, the motion of two colliding molecules is
strictly quantized. Recently, atom-exchange reactions were observed in a
trapped ultracold gas of KRb molecules. In an external electric field, these
exothermic and barrierless bimolecular reactions, KRb+KRb -> K2+Rb2, occur at a
rate that rises steeply with increasing dipole moment. Here we show that the
quantum stereodynamics of the ultracold collisions can be exploited to suppress
the bimolecular chemical reaction rate by nearly two orders of magnitude. We
use an optical lattice trap to confine the fermionic polar molecules in a
quasi-two-dimensional, pancake-like geometry, with the dipoles oriented along
the tight confinement direction. With the combination of sufficiently tight
confinement and Fermi statistics of the molecules, two polar molecules can
approach each other only in a "side-by-side" collision, where the chemical
reaction rate is suppressed by the repulsive dipole-dipole interaction. We show
that the suppression of the bimolecular reaction rate requires quantum-state
control of both the internal and external degrees of freedom of the molecules.
The suppression of chemical reactions for polar molecules in a
quasi-two-dimensional trap opens the way for investigation of a dipolar
molecular quantum gas. Because of the strong, long-range character of the
dipole-dipole interactions, such a gas brings fundamentally new abilities to
quantum-gas-based studies of strongly correlated many-body physics, where
quantum phase transitions and new states of matter can emerge.Comment: 19 pages, 4 figure
Experimental investigation of ultracold atom-molecule collisions
Ultracold collisions between Cs atoms and Cs2 dimers in the electronic ground
state are observed in an optically trapped gas of atoms and molecules. The Cs2
molecules are formed in the triplet ground state by cw-photoassociation through
the outer well of the 0g-(P3/2) excited electronic state. Inelastic
atom-molecule collisions converting internal excitation into kinetic energy
lead to a loss of Cs2 molecules from the dipole trap. Rate coefficients are
determined for collisions involving Cs atoms in either the F=3 or F=4 hyperfine
ground state and Cs2 molecules in either highly vibrationally excited states
(v'=32-47) or in low vibrational states (v'=4-6) of the a ^3 Sigma_u^+ triplet
ground state. The rate coefficients beta ~10^{-10} cm^3/s are found to be
largely independent of the vibrational and rotational excitation indicating
unitary limited cross sections.Comment: 4 pages, 3 figures, submitted for publicatio
Dipolar collisions of polar molecules in the quantum regime
Ultracold polar molecules offer the possibility of exploring quantum gases
with interparticle interactions that are strong, long-range, and spatially
anisotropic. This is in stark contrast to the dilute gases of ultracold atoms,
which have isotropic and extremely short-range, or "contact", interactions. The
large electric dipole moment of polar molecules can be tuned with an external
electric field; this provides unique opportunities such as control of ultracold
chemical reactions, quantum information processing, and the realization of
novel quantum many-body systems. In spite of intense experimental efforts aimed
at observing the influence of dipoles on ultracold molecules, only recently
have sufficiently high densities been achieved. Here, we report the observation
of dipolar collisions in an ultracold molecular gas prepared close to quantum
degeneracy. For modest values of an applied electric field, we observe a
dramatic increase in the loss rate of fermionic KRb molecules due to ultrcold
chemical reactions. We find that the loss rate has a steep power-law dependence
on the induced electric dipole moment, and we show that this dependence can be
understood with a relatively simple model based on quantum threshold laws for
scattering of fermionic polar molecules. We directly observe the spatial
anisotropy of the dipolar interaction as manifested in measurements of the
thermodynamics of the dipolar gas. These results demonstrate how the long-range
dipolar interaction can be used for electric-field control of chemical reaction
rates in an ultracold polar molecule gas. The large loss rates in an applied
electric field suggest that creating a long-lived ensemble of ultracold polar
molecules may require confinement in a two-dimensional trap geometry to
suppress the influence of the attractive dipolar interactions
Resonant collisional shielding of reactive molecules using electric fields
Full control of molecular interactions, including reactive losses, would open
new frontiers in quantum science. Here, we demonstrate extreme tunability of
chemical reaction rates by using an external electric field to shift excited
collision channels of ultracold molecules into degeneracy with the initial
collision channel. In this situation, resonant dipolar interactions mix the
channels at long range, dramatically altering the intermolecular potential. We
prepare fermionic potassium-rubidium (KRb) molecules in their first excited
rotational state and observe a three orders-of-magnitude modulation of the
chemical reaction rate as we tune the electric field strength by a few percent
across resonance. In a quasi-two-dimensional geometry, we accurately determine
the contributions from the three lowest angular momentum projections of the
collisions. Using the resonant features, we shield the molecules from loss and
suppress the reaction rate by up to an order of magnitude below the background
value, realizing a long-lived sample of polar molecules in large electric
fields.Comment: 17+4 pages, 4+1 figure
Determination of the moments of the proton charge density
A global analysis of proton electric form factor experimental data from
Rosenbluth separation and low squared four-momentum transfer experiments is
discussed for the evaluation of the spatial moments of the proton charge
density based on the recently published integral method \cite{Hob20}. Specific
attention is paid to the evaluation of the systematic errors of the method,
particularly the sensitivity to the choice of the mathematical expression of
the form factor fitting function. Within this comprehensive analysis of proton
electric form factor data, the moments of the proton charge density are
determined for integer order moments, particularly: =0.682(02)(11)~fm, =0.797(10)(58)~fm, and =1.02(05)(31)~fm. This analysis leads to the
proton charge radius 0.8459(12)(76)~fm once relativistic
effects are taken into account.Comment: 10 pages, 3 figure
Long range forces between polar alkali diatoms aligned by external electric fields
Long range electrostatic, induction and dispersion coefficients including
terms of order have been calculated by the sum over states method
using time dependent density functional theory. We also computed electrostatic
moments and static polarizabilities of the individual diatoms up to the
octopole order using coupled cluster and density functional theory. The
laboratory-frame transformed electrostatic moments and van der Waals
coefficients corresponding to the alignment of the diatomic molecules were
found. We use this transformation to obtain the coupling induced by an external
DC electric field, and present values for all XY combinations of like polar
alkali diatomic molecules with atoms from Li to Cs. Analytic solutions to the
dressed-state laboratory-frame electrostatic moments and long range
intermolecular potentials are also given for the DC low-field limit
Tuning of dipolar interactions and evaporative cooling in a three-dimensional molecular quantum gas
Ultracold polar molecules possess long-range, anisotropic and tunable dipolar interactions, providing opportunities to probe quantum phenomena that are inaccessible with existing cold gas platforms. However, experimental progress has been hindered by the dominance of two-body loss over elastic interactions, which prevents efficient evaporative cooling. Although recent work has demonstrated controlled interactions by confining molecules to a two-dimensional geometry, a general approach for tuning molecular interactions in a three-dimensional stable system has been lacking. Here we demonstrate tunable elastic dipolar interactions in a bulk gas of ultracold 40K87Rb molecules in three dimensions, facilitated by an electric field-induced shielding resonance that suppresses the reactive loss by a factor of 30. This improvement in the ratio of elastic to inelastic collisions enables direct thermalization. The thermalization rate depends on the angle between the collisional axis and the dipole orientation controlled by an external electric field, a direct manifestation of the anisotropic dipolar interaction. We achieve evaporative cooling mediated by the dipolar interactions in three dimensions. This work demonstrates full control of a long-lived bulk quantum gas system with tunable long-range interactions, paving the way for the study of collective quantum many-body physics
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